Toxicological profile for mercury agency for toxic substances. First aid measures first aid measures general advice if symptoms persist, call a physician. Diethylene glycol mono methyl ether material safety. Organic mercury compound such as methyl mercury or dimethyl mercury are more dangerous. Socmi hap volatile hap organic hap ozone depleting mercuric acetate the information presented above is offered for informational purposes only. Material safety data sheet mercuryi nitrate dihydrate. Monomethyl paminophenol sulfate creates many skin problems, and allergies to it are frequent although this is thought to be due to the presence of paraphenylene diamine as a contaminant. Mercury safety data sheet according to the federal final rule of hazard communication revised on 2012 hazcom 2012 112320 en english 29 brain. This msds, and the associated product, is intended for use only by technically qualified persons, and at their own discretion and risk. Pdf total and monomethylmercury and major ions in coastal.
Inorganic forms are converted by microbial action in the atmosphere to methyl mercury. Exposure to mercury or mercury compounds can cause discoloration on the front surface of the lens, which does not interfere with. Dimethylmercury is capable of permeating many materials, including plastic and rubber compounds. Stability of dimethyl mercury in seawater and its conversion. Description of first aid measures general in all cases of doubt, or when symptoms persist, seek medical attention. Hg cycles through the environment and can ulmately be converted into di. Organic mercury is one of three forms of mercury listed in teach. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Symptoms of exposure to this compound include ataxia, paralysis and incoordination.
In the past, an organic mercury compound called phenylmercury was used in some commercial products. Methyl mercury standard, methyl mercury ion methyl quecksilberion methylquecksilberkation. Mercury certified acs revision date 17jan2018 waste disposal methods chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Methylmercury mehg casrn 22967926 iris us epa, ord. Material safety data sheet section methyl isobutyl carbinol 1 chemical product and company identification msds name. Mercury msds page 1 of 10 material safety data sheet prepared to u.
Methyl azide in the presence of mercury was shown to be potentially explosive. Death in this phase usually occurs as a result of kidney failure. Methyl zide in the presence of mercury was shown to be potentially explosive. Potential sources of monomethyl mercury in arctic and. Methyl mercury was available in the form of several salts. Store in a cool dry ventilated location, away from sources of ignition or other incompatible conditions and chemicals. Identification of the substancemixture and of the companyundertaking product name. Methyl mercury in zooplankton the role of size, habitat, and food quality article pdf available in canadian journal of fisheries and aquatic sciences 5910. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Laboratory procedure manual centers for disease control. The information in cameo chemicals comes from a variety of data sources.
This functional group is composed of a methyl group bonded to a mercury. The chronic effects of mercury poisoning include stomatitis, excessive salivation, weight loss, dermatitis, loosening of teeth and pain on chewing. Show this material safety data sheet to the doctor in attendance. Photographic processing hazards, by michael mccann, ph. Methyl red ts safety data sheet according to federal register vol. The system generates the hydroxonium cation due to the interaction, which is a demethylating agent for methylmercury. Methyl orange indicator solution material safety data sheet sdsmsds. Male icr and b6c3f1 mice exposed to methylmercuric chloride in the diet had an increased incidence of renal adenomas, adenocarcinomas and carcinomas. All forms of mercury hg metal, vapor, inorganic, or organic are converted to methyl mercury. Exposure to mercury or mercury compounds can cause discoloration on the front surface of the lens, which does not interfere with vision. Safety data sheet monomethylamine 40% aqueous solution mma40 version 1. Chronic ingestion may cause accumulation of mercury in body tissues.
Pdf marine fog water samples were collected over two summers 20142015 with active strand collectors cascc at eight coastal sites from humboldt to. Identification product name mercury ii iodide cat no. Methylmercury is formed from inorganic mercury by the action of microbes that live in aquatic systems including lakes, rivers, wetlands, sediments, soils and the open ocean. Dimethyl mercury is an alkyl mercury compound that is a.
Identification product name mercury filled thermometers and hydrometers synonyms colloidal mercury. Show this safety data sheet to the doctor in attendance. May be absorbed through the skin in harmful amounts. This product has been classified in accordance with the. Dimethylmercury c h 3 2 hg is an organomercury compound. It exists in three forms that have different properties, usage, and toxicity. Contact with mercury or mercury compounds can cause ulceration of the conjunctiva and cornea. The first deposits of mercury in rat brain became apparent 10 days after exposure to 16 mgl of methylmercury chloride in drinkingwater.
Mercury centers for disease control and prevention. The average halftime for clearance of mercury for different parts of the human body is as follows. Hydrazine anhydrous,monomethyl hydrazinemmh,unsdimethyl. A mixture of the dry carbonyl and oxygen will explode on vigorous shaking with mercury. It affects the immune system, alters genetic and enzyme systems, and damages the nervous system, including coordination and the senses of touch, taste, and sight. The alimentary effects of many mercury compounds are so rapid that the course and outlook is largely determined by events within the first 510 minutes.
Histochemical localization by silver amplification of mercury showed a different distribution. Very hazardous in case of ingestion, of inhalation. Indication of any immediate medical attention and special treatment needed no additional information available section 5. Osha no component of this product present at levels greater. Request pdf stability of dimethyl mercury in seawater and its conversion to monomethyl mercury dimethyl mercury dmhg is commonly detected in the worlds oceans, but little is known about the. Anhydrous hydrazine ah monomethyl hydrazine mmh uns dimethyl hydrazine udmh hydrogen peroxideh 2 o 2 dinitrogen tetroxiden 2 o 4 hydroxylterminated polybutadienehtpb ammonium perchlorate ap e thylamine 1anhydrous hydrazine. Skin contact wash off immediately with plenty of water for at least 15 minutes. Chronic ingestion or inhalation of mercury salts can affect the brain, blood, endocrine system, behaviorcentral nervous system with symptoms including tremors. From what i have read before, mostly it is because mercury accumulation occurs easily in organic mercury. The deposits were found initially in the brain stem, then in the cerebral cortex and supraoptic nucleus, and finally in the cerebellum and thalamus. We hypothesize that monomethyl mercury mmhg is produced deep in water columns and in ocean sediments. This methylmercury production has been primarily attributed to anaerobic bacteria in the sediment.
Anthropogenic sources and natural processes release hg into the environment. Material safety data sheet methylmercuryii chloride sc255303 hazard alert code key. Safety data sheet creation date 20aug2014 revision date 20aug2014 revision number 1 1. The toxic effects of mercury depend on its chemical form and the route of exposure. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Never give anything by mouth to an unconscious person. Much of the mercury deposited on land, appears to revaporize within a day or two, at least in areas substantially heated by sunlight. Why organic mercury compound is more dangerous than. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. Mercury in other organs is removed slowly from the body via the kidneys. The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication. Mercury and ammonia can produce an explosive compound.
Accidental release measures small spill large spill. Other symptoms include nausea, abdominal pain, vomiting, diarrhea, shock, kidney damage, nervous disturbances, tremors of the hands, insomnia, loss of memory, irritability, depression, loosening of teeth and excessive salivation. Extreme high moderate low section 1 chemical product and company identification product name methylmercuryii chloride statement of hazardous nature considered a hazardous substance according to osha 29 cfr 1910. Mercury aa standard, ppm 1ml 1mg hg safety data sheet according to federal register vol. Methyl orange indicator solution material safety data. Hazards identification this material is considered to be hazardous according to regulat ory guidelines see msds section 15. Based on inadequate data in humans and limited evidence of carcinogenicity in animals. All forms of mercury are quite toxic, and each form exhibits different health effects. Usa home product directory materials science metal and ceramic science metals mercury. Our team of scientists has experience in all areas of research including life science, material science, chemical synthesis, chromatography, analytical and many others. Monomethyl mercury in polar oceans photo by sohei matsuda. A highly volatile, reactive, flammable, and colorless liquid, dimethylmercury is one of the strongest known neurotoxins, with a quantity of less than 0. The potential interaction surface between polyhydrated monomethyl mercury cation and 1chloro2. Mechanism of mercury monomethyl cation detoxication in the.
Global warming and increased ultraviolet radiation may affect the global budget of methylmercury, including its formation and degradation in both biotic and abiotic environments. A fullface piece respirator with a mercury vapor or chlorine gas cartridge may be worn up to 50 times the exposure. In addition to this chemical summary, there are separate chemical summaries for inorganic mercury and for elemental mercury. Pdf methyl mercury in zooplankton the role of size. Whether cns damage is due to methyl mercury or inorganic mercury, or both, is still controversial 4.
Chronic exposure to mercury may cause permanent central nervous system damage, fatigue, weight loss, tremors, personality changes. Methyl ethyl ketone 78 93 3 100% all concentrations are percent by weight unless material is a g as. Safety data sheet mercury metallic sds revision date. The three forms are called elemental or metallic mercury, inorganic mercury compounds, and organic mercury compounds. Development of improved sample preparation methods for. Mercury, monomethyl mercury, and dissolved organic carbon. Of alkyl mercury compounds, ethyl and methyl compounds have been used as pesticides. The general term methylmercury is used throughout this text to represent monomethylmercury compounds. The hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. Mercury mercury is an element and a metal that is found in air, water, and soil. Uses advised against no information available details of the supplier of the safety. Mercury compounds hazard summary mercury exists in three forms. Metallic mercury recommended use laboratory chemicals. Methyl mercury readily crosses the bloodbrain barrier due to its lipid solubility and accumulates in the brain where it is slowly converted to inorganic mercury.